Conductivity (EC) measures the ability of water to conduct an electrical current. It depends on the concentration of ions, their mobility, and their charge. Units: µS/cm (microsiemens per centimeter) or mS/cm.
It is a direct physical measurement: an AC voltage is applied between two electrodes, and the resulting current is measured.
Example: pure water ≈ 0.055 µS/cm; tap water 200–800 µS/cm; seawater ≈ 50 mS/cm.
TDS represents the total mass of dissolved substances (inorganic salts, small amounts of organic matter) in water. Units: mg/L or ppm (parts per million).
TDS is typically measured gravimetrically: evaporating a filtered water sample and weighing the residue. However, for routine use, TDS is estimated from conductivity using a conversion factor.
Example: distilled water TDS 0–1 mg/L; tap water 100–500 mg/L; brackish water >5000 mg/L.
Because dissolved ions carry electrical current, there is a strong empirical correlation between TDS (mass concentration) and conductivity. However, the relationship is not universal — it depends on the mixture of ions present.
where k is the conversion factor, typically ranging from about 0.4 to 1.0. For many natural waters, a factor of 0.65–0.7 is common.
| Water type / solute | Typical k factor (µS/cm → mg/L) | Notes |
|---|---|---|
| Natural freshwater (rivers, lakes) | 0.65 – 0.70 | Mixed ions, dominated by Ca²⁺, HCO₃⁻, SO₄²⁻ |
| NaCl dominant (seawater, brine) | 0.50 – 0.55 | Sodium chloride has higher conductivity per mg/L |
| KCl solutions (laboratory) | 0.50 – 0.52 | Often used for calibration |
| Mixed wastewater | 0.60 – 0.80 | Depends on industrial contribution |
| Boiler feedwater (ultra‑pure) | ~0.50 – 0.60 | Very low ionic strength, sensitive to trace ions |
Note: For ultra‑pure water (EC < 10 µS/cm), the factor becomes unstable and highly dependent on the specific ions present (often CO₂). Direct TDS measurement by gravimetry is recommended.
For routine monitoring where approximate TDS is acceptable, use a factor typical for your water type:
Repeat periodically (e.g., seasonally) if water chemistry varies.
| Conductivity (µS/cm) | Estimated TDS (mg/L) with k=0.65 | Typical water type |
|---|---|---|
| 0.055 | ~0.04 | Ultra‑pure water |
| 10 | 6.5 | Distilled water |
| 100 | 65 | Rainwater, very soft |
| 300 | 195 | Soft to moderate freshwater |
| 500 | 325 | Average river water |
| 800 | 520 | Hard freshwater / tap water |
| 1500 | 975 | Brackish / high‑mineral water |
| 5000 | 3250 | Saline / some industrial streams |
| 50000 | 32500 | Seawater (approx.) |
In such cases, rely on direct TDS measurement (gravimetric) or use ion‑specific sensors.
Most handheld "TDS meters" are actually conductivity meters with a fixed conversion factor (usually 0.5, 0.64, or 0.7) programmed inside. They measure EC and internally multiply by the chosen factor. This is why:
Better practice: Use a true conductivity meter, then apply the correct factor for your specific application.
Some regulations (e.g., drinking water standards, discharge permits) specify TDS limits, not conductivity. In such cases, you must either:
The USEPA and EU Water Framework Directive accept the correlation method if properly documented.
Conductivity and TDS are intimately related but not identical. Conductivity is a fast, inexpensive measurement, while TDS provides a mass‑based metric. The conversion factor bridges them, but it is not universal — it depends on water chemistry. For accurate work, determine your own factor, be aware of its limitations, and never treat a TDS meter reading as absolute truth without understanding the underlying factor. Use conductivity as a dynamic proxy, and verify with gravimetric TDS when precision matters.
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